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51.
We have carried out a theoretical study of the simplest possible, second-order, chemical destruction process in the atmospheric surface layer. The model describes the destruction of two gases emanating from the surface with the same molecular flux. Although this situation seems artificial with no counterpart in the real atmosphere, the results shed light on some fundamental problems. For example, it is possible to specify boundary conditions, with the concentrations and the fluxes at a given height away from the surface, which lead to unrealistic solutions with infinite surface fluxes. A method to describe and separate the consistent solutions for this process was developed. It is in general of particular interest from an experimental point of view since it is not possible to measure fluxes right at the surface: if a measurement of flux and concentration in a given height requires infinite surface fluxes there is something wrong with the data. We expect that such problems will be inherent in more complex reactions schemes, such as the NO-NO2-O3 triad. Just as in first-order destruction processes, the Damköhler ratio will enter the turbulent diffusivity, but where this ratio is concentration independent for first-order processes, the present second-order model implies that the Damköhler ratio is proportional to the concentration. In the study of first-order processes it was found that the Damköhler correction to the turbulent diffusivity is of minor importance from an experimental point of view. We arrive at the same conclusion in this particularly simple study of second-order destruction. In other words, this work may be considered a further development of a previous study of the first-order destruction of a passive scalar. The model and the method we develop to solve the corresponding nonlinear differential equations are considered a preliminary study for developing tools to deal with more complicated atmospheric processes. Also, the results obtained may serve as a “calibration case” for more elaborate simulations. 相似文献
52.
Hans Petter Sejrup Haflidi Haflidason Dorthe Klitgaard Kristensen Sigfus J. Johnsen 《第四纪科学杂志》1995,10(4):385-390
Planktonic foraminiferal evidence suggests that the ocean front systems between Polar and Atlantic surface waters in the Norwegian Sea generally were located closer to Greenland during Oxygen Isotope Substage 5e than in the Holocene. During both these periods oscillations have occurred in the position of the fronts. In the western Norwegian Sea region, the substage 5e influence of warm Atlantic waters was interrupted by a return to polar conditions. These findings support both ice-core data and evidence from Europe that the last interglacial was a period of rapid climatic shifts. 相似文献
53.
TenCate J.A. Muir T.G. Caiti A. Kristensen A. Manning J.F. Shooter J.A. Koch R.A. Michelozzi E. 《Oceanic Engineering, IEEE Journal of》1995,20(4):300-310
The problem of locating very low frequency sound sources in shallow water is made difficult by the interaction of propagating acoustic waves with the sea floor. Slow wave speeds and the attendant short wavelengths suggest that low frequency beamforming and source localization with sea floor geophones can be accomplished with relatively small arrays when compared with hydrophone arrays in the water column. To test the feasibility of this approach, experiments were carried out in the shallow water of the Malta Channel of the Straits of Sicily where the Scholte wave speed was some 10 to 20 times slower that the speed of sound in water. A linear array of ten vertically gimballed geophones was deployed and measurements were made on propagating seismic wave fields generated by explosive shots. The resulting directivities, beam patterns, and sidelobe characteristics are in excellent agreement with array theory, which suggests that coherent processing is a viable technique on which to base new applications for seismic arrays on the sea floor. Supporting materials on the geophysics of Scholte waves and calculations of the wave field at the site are presented 相似文献
54.
Intensive measurements of the fluxes of phosphorus (P) and of P retention were carried out in a Danish lowland watershed (Gjern Å) during two hydrological years (June 1987 to May 1989). Seasonal and short-term variations of P concentrations were measured by intensive automatic sampling covering P fluxes from the entire Gjern Å watershed and two subcatchments: the Gelbæk and Lake Søbygård. Moreover, infrequent sampling was performed in all major tributaries of the river system. Transport of P compounds (dissolved and particulate P) exposed a seasonal pattern which was highly affected by flow conditions, instream processes, as well as point and non-point sources. Stormflow P transport during the two study years (1987-8 and 1988-9) constituted 56 and 61% in the Gelbæk, respectively, compared with 25 and 23% in the Gjern Å, respectively. Particulate P transport in the Gelbæk constituted 56 and 75% of annual total P transport during the two years compared with 77 and 75% in the Gjern Å. The magnitude of monthly baseflow and stormflow total P loads was significantly correlated with the mean monthly discharge during baseflow and stormflow in the Gelbæk, whereas only stormflow loads were correlated to discharge in the Gjern Å. In situ measurements of retention showed that the maximum amount of P stored in the Gelbæk during summer (June to August) was 22gPm?2 (1988) compared with 27gPm?2 (1987) in the Gjern Å. Lake Søbygård was a P source during summer but a P sink during winter and on an annual basis the net P released was 810 and 1420 kg, which corresponded to 7 and 20% of the annual P export from the watershed, respectively. Retention constituted about 30% of gross P transport in the Gelbæk during summer compared with 20% in the Gjern Å. Resuspension of retained P during stormflows in September 1987 constituted 94% of the stormflow P transport and 54% of the total P transport. Monthly total P and dissolved reactive P (DRP) mass balances for the main channel of the Gjern Å revealed a significant DRP retention over 17 months (p < 0.05) caused by P adsorption on sediments and biological uptake. On an annual basis the main channel was a sink of DRP (1220 and 1660 kg P) but a source of total P (3440 and 1000 kg P). implying that the channel is an important source of particulate P. Bank erosion proved to be a significant P source in the main channel of Gjern Å, whereas P delivery from soil erosion was possibly of minor importance. The annual non-point P export from two intensively sampled catchments was significantly higher (0.89 and 0.45 kg Pha?1 yr?1) than from the five extensively sampled subbasins (0.43 and 0.17 kg Pha?1 yr?1). No significant relationship could be established between non-point P export and the proportion of arable land and soil type. Only for the wet year of 1987-8 was a significant relationship established between non-point P export and the P load from scattered dwellings outside sewage areas in five subbasins. 相似文献
55.
L. Kristensen 《Boundary-Layer Meteorology》1979,16(3):145-153
It is demonstrated that the longitudinal spectral coherence differs significantly from the transversal spectral coherence in its dependence on displacement and frequency. An expression for the longitudinal coherence is derived and it is shown how the scale of turbulence, the displacement between observation sites and the turbulence intensity influence the results. The limitations of the theory are discussed. 相似文献
56.
Sulphidic mine waste disposed in marine environments constitutes an environmental risk to aquatic life due to potential uptake and accumulation of heavy metals in biota. Fiord sediments near the former Black Angel Mine in West Greenland are contaminated by lead and zinc as a result of submarine tailings disposal in 1973-1990. In 1999 cores were taken up to 10 km away from the disposal area. Analyses include heavy metals, radiochemical dating (210Pb) and high-resolution foraminiferal stratigraphy. The mining operation resulted in significant changes in the assemblage composition. In addition, up to 20% of the Melonis barleeanus population found in sediment deposited during nearby tailings disposal was deformed compared to a natural background of less than 5%. Throughout cores representing the last 100 years of sedimentation, the total numbers and frequency of morphological abnormalities among M. barleeanus revealed some correlation with heavy metals concentrations (up to r2 = 79%). We conclude that abnormalities among foraminifera may represent a useful biomarker for evaluating trends in the biological impact resulting of submarine tailings disposal as well as long-term environmental impact and subsequent recovery. 相似文献
57.
Cintia O. Quintana Caroline Raymond Francisco J. A. Nascimento Stefano Bonaglia Stefan Forster Jonas S. Gunnarsson Erik Kristensen 《Estuaries and Coasts》2018,41(6):1766-1781
A 4-week laboratory experiment investigated the behaviour (survival and bioirrigation) and impact of the invasive polychaetes Marenzelleria viridis, M. neglecta and M. arctia on sediment-water solutes exchange, porewater chemistry, and Fe and P interactions in high-salinity sandy sediment (HSS) and low-salinity muddy sediment (LSM) from the Baltic Sea. M. viridis showed deep burrowing with efficient bioirrigation (11 L m?2 day?1) and high survival (71%) in HSS, while M. arctia exhibited shallow burrowing with high bioirrigation (12 L m?2 day?1) and survival (88%) in LSM. M. neglecta behaved poorly in both ecological settings (bioirrigation, 5–6 L m?2 day?1; survival, 21–44%). The deep M. viridis bioirrigation enhanced total microbial CO2 (TCO2) production in HSS by 175% with a net efflux of NH4+ and PO43?, at rates 3- to 27-fold higher than for the other species. Although the shallow and intense bioirrigation of M. arctia in LSM stimulated microbial TCO2 production to some extent (61% enhancement), the nutrient fluxes close to zero indicate that it effectively prevented the P release. Porewater Fe:PO43? ratios revealed that the oxidizing effect of M. arctia bioirrigation increased the PO43? adsorption capacity of LSM twofold relative to defaunated controls while no buffering of PO43? was detected in M. viridis HSS treatment. Therefore, the different behaviour of the three species in various environments and the sharp contrast between M. viridis and M. arctia effects on C, N and P cycling must be considered carefully when the ecological role of Marenzelleria species in the Baltic Sea is evaluated. 相似文献
58.
Gil Penha-Lopes Fabrizio Bartolini Samwel Limbu Stefano Cannicci Erik Kristensen Jos Paula 《Marine pollution bulletin》2009,58(11):1694-1703
The effect of different organic-rich sewage concentration (0%, 20% and 60% diluted in seawater) and absence or presence of mangrove trees on the survival, bioturbation activities and burrow morphology of fiddler crabs species was assessed. After 6 months, males of both species always showed higher survival (80%) when compared to females (20%). Crabs inhabiting pristine conditions achieved higher survival (67–87%) than those living in sewage-exposed mesocosms (40–71%). At 60% sewage loading, fiddler crabs processed less sediment (34–46%) during feeding and excavated slightly more sediment (45–80%) than at pristine conditions. While percent volume of the burrow chambers increased (13–66%) at contaminated mesocosms for both vegetation conditions, burrows were shallower (33%) in bare cells loaded with sewage. The results show that fiddler crabs presented moderate mortality levels in these artificial mangrove wetlands, but mainly in sewage impacted cells. However, they still function as ecosystem engineers through bioturbation activities and burrow construction. 相似文献
59.
Leif Kahl Kristensen 《Celestial Mechanics and Dynamical Astronomy》2009,105(4):275-287
Initial orbit determination by least squares of N observations is essentially a linear problem if the coordinates x
0 and x
1 at two standard epochs are used as elements. The orbit of a main belt object is approximated within the observational errors
by a third degree polynomial during a month. A 4-observation orbit is useful for the initial linking between two nights. Parallax
is treated rigorously and future simultaneous space and Earth based observations determine the critical distance directly.
The N-observation method is a great simplification of the classical 3-observation orbit followed by a differential correction by
N observations. 相似文献
60.